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31.
《自然科学进展(英文版)》2019,29(1):28-31
Providing a suitable contact interface, where a high conductivity material with a desirable coefficient of thermal expansion(CTE) adjoins the target micro-electric devices, is very crucial to optimize the properties and service life of the relevant instruments. Regrettably, a high conductivity, low thermal expansion and relatively inexpensive material is very rare. Composites, fortunately, can offer a method to design materials with adjustable properties by mixing two or more diverse constituents. In this paper, high conductivity composites with adjustable thermal expansion were successfully prepared by a high-pressure synthesis. The composites are based on combining La(Fe,Si)_(13)-based compounds, the materials showing a giant, isotropic negative thermal expansion(NTE) properties, within Cu matrix. The La(Fe,Si)_(13)-based compounds were used to adjust the CTE of the composites, while the Cu phase is in charge of tuning the thermal conductivity properties. Thus, by changing the relative amount of the two components, the composites with high conductivities and adjustable CTE were achieved. Furthermore, the thermal expansion and magnetic properties of the composites were investigated by a physical property measurement system. The present results highlight the potential applications of the Cu-based high conductivity composites with room-temperature NTE properties in the thermal contacts to various semiconductor and microelectronic devices. 相似文献
32.
通过种子生长法合成了不同形态的金纳米粒子,之后加入至氧化石墨烯水分散液中超声震荡得到不同形状的氧化石墨烯-金纳米粒子复合物。运用扫描电子显微镜、X射线光电子能谱、拉曼光谱等表征手段,探究复合物的表面结构、结合能与电荷状态,通过对对硝基苯酚的检测以表征其拉曼活性,并分析造成不同增强效果的原因。结果表明,氧化石墨烯-金纳米粒子复合物表现出良好的表面增强拉曼活性,可以成功地检测到10-5 mol/L的对硝基苯酚,且复合物的表面增强拉曼活性因金粒子的形状不同而有所差异。 相似文献
33.
The high mechanical and thermal performance of poly p-phenylene- 2, 6-benzobisoxazole ( PBO ) fiber provides great potential applications as reinforcement fibers for composites. A composite of PBO fiber and epoxy resin has excellent electrical insulation properties, therefore, it is considered to be the best choice for the reinforcement in high magnetic field coils for pulsed magnetic fields up to 100 T.However, poor adhesion between PBO fiber and matrix is found because of the chemically inactive and/or relatively smooth surface of the reinforcement fiber preventing efficient chemical bonding in the interface, which is a challenging issue to improve mechanical properties. Here, we report the surface modification of PBO fibers by ultraviolet (UV)irradiation, O2 and NH3 plasma, as well as acidic treatments. The interfacial adhesion strength values of all the treatments show the similar level as determined for aramid fibers by pull-out tests, a significant impact on fibermatrix-adhesion was not achieved. The surface free energy and roughness are increased for both sized and extracted fibers after plasma treatments together with maleic anhydride grafting. The sized fiber shows marginal improvement in adhesion strength and no change in fiber tensile strength because of the barrier effect of the finish.For the extracted fiber, different surface treatments either show no apparent effect or cause reduction in adhesion strength. Atomic force microscopy (AFM) topography analysis of the fracture surfaces proved adhesive failure at the fiber surface. The fiber surface roughness is increased and more surface flaws are induced, which could result in coarse interface structures when the treated fiber surface has no adequate wetting and functional groups. The adhesion failure is further confirmed by similar adhesion strength and compression shear strength values when the fiber was embedded in various epoxy resins with different temperature behavior. The tensile strength of fiber is sensitive to surface treatment conditions as revealed by a bimodal Weibull statistical distribution analysis. Considerable strength reduction occurred, particularly for cases of acidic and plasma treatments, while UV irradiation shows the better ability to retain fiber strength. 相似文献
34.
Transition from Multiple Macro-Cracking to Multiple Micro-Cracking in Cementitious Composites 总被引:1,自引:0,他引:1
This paper presents an experimental study of the possibility of transition from multiple macro-cracking to multiple micro-cracking in cementitious composites.Conventional polyvinyl alcohol fiber reinforced cementitious composites normally exhibit macroscopic strain-hardening and multiple cracking after the first cracks appear.However,the individual crack width at the saturated stage is normally 60 to 80 μm.In the current study,the effect of fine aggregate size on the cracking performance,especially the individual crack width in the strain-hardening stage was studied by bending tests.The results show that the individual crack widths can be reduced from 60-80 μm to 10-30 μm by modifying the particle size of the fine aggregates used in the composites. 相似文献
35.
在实验的基础上,提出冷轧钢基复合材料的轧制力计算模型,并由此推导冷轧钢基复合材料的轧制力计算公式.采用该公式计算出的轧制力与实验值基本符合. 相似文献
36.
PZT/环氧树脂0—3型压电复合材料性能的研究 总被引:9,自引:0,他引:9
制备了以环氧树脂为基体,不同PZT材料为压电相的两种0-3型压电复合材料。研究了极化工艺参数和陶瓷粉末对压电系数d-33的影响,结果表明,复合材料的压电系数d-33先随极化合场E和极化时间t的增加而增加,之后趋于恒定。PZT体积含量增加,介电常数ε2减小,则复合材料压电系数d-33增加。 相似文献
37.
38.
A STRUCTURAL ANALYSIS OF THREE-DIMENSIONAL BRAIDS 总被引:1,自引:0,他引:1
This paper describes a study of three-dimensional braids produced by a four-step 1 × 1 method. An analytical approach is employed in conjunction with experimental investigations to establish the relationship between the braid structure and braiding parameters. Based on microscopic observations, we divide a three-dimensional braid structure into three representative regions, i.e., the interior, surface and corner, and treat the three regions, respectively. Three types of microstructural unit-cell models are then established. The surface characteristics and the relationship between the interior and surface unit-cells have been derived. Good agreement has been obtained between the calculated and measured values of fiber volume fraction of the braided composite samples. 相似文献
39.
40.
界面反应层是影响SiC纤维(SiCf)增强钛基复合材料力学性能的重要因素,本文研究了SiCf/Ti2AlNb复合材料在热等静压成型以及热暴露过程中的界面反应、界面元素分布规律和界面热稳定性.研究结果表明:SiCf/Ti2AlNb复合材料内部元素扩散形成的界面产物主要为TiC,在热暴露过程中出现了TiSi2和NbSi2相.SiCf/Ti2AlNb复合材料界面反应层的厚度长大符合Arrhenius定律,其界面反应层厚度长大速率随着热暴露温度的升高而增加.界面反应层长大激活能为24.27kJ/mol,界面层长大频率因子为2.80×10-4 m/s1/2.SiCf/Ti2AlNb复合材料界面在700℃及以下温度具备良好的热稳定性. 相似文献